5 years ago

Calcium stilbene complexes: structures and dual reactivity

Calcium stilbene complexes: structures and dual reactivity
Gerd Ballmann, Holger Elsen, Sjoerd Harder, Ana Escalona, Andrea Causero
Addition of a calcium hydride complex to diphenylacetylene gave a complex in which the stilbene dianion symmetrically bridges two Ca2+ ions. With H2, this complex reacts as a double Bronsted base. In reaction with I2 it provides two electrons.

Publisher URL: http://feeds.rsc.org/~r/rss/CC/~3/rJ6LDzNFPaw/C7CC05792J

DOI: 2017/CC/C7CC05792J

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