Organic Letters
Organic Letters
5 years ago

Convergent Synthesis of the ent-ZA′B′C′D′-Ring System of Maitotoxin

Convergent Synthesis of the ent-ZA′B′C′D′-Ring System of Maitotoxin
Tatsuo Saito, Masayuki Morita, Mikiko Sodeoka, Tadashi Nakata, Hiroyuki Koshino
Stereoselective synthesis of the ent-ZA′B′C′D′-ring system of maitotoxin has been accomplished through a convergent strategy utilizing Suzuki–Miyaura cross coupling reaction of ZA′-ring alkylborane and C′D′-ring (Z)-vinyl iodide, and subsequent construction of the B′-ring by reduction of the O,S-acetal.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b01301

DOI: 10.1021/acs.orglett.7b01301

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