4 years ago

Molecular Routes to Group IV Magnesium and Calcium Nanocrystalline Ceramics

Molecular Routes to Group IV Magnesium and Calcium Nanocrystalline Ceramics
Dominik Bykowski, Piotr Sobota, Józef Utko, Anna Drąg-Jarząbek, Tadeusz Lis, Rafał Petrus
In this study, we prepare group IV magnesium and calcium oxide materials using Cp2M′Cl2 (M′ = Ti, Zr, Hf) and M(OEt)2 (M = Mg, Ca) as metal sources. We demonstrated that metal alkoxides and their organometallic derivatives can be easily used to synthesize molecular precursors for the preparation of numerous of group IV alkaline-earth ceramics as functional nanomaterials with unique properties.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01772

DOI: 10.1021/acs.inorgchem.7b01772

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