Inorganic Chemistry
Inorganic Chemistry
5 years ago

Magnetic Interaction Affecting the Zero-Field Single-Molecule Magnet Behaviors in Isomorphic {NiII2DyIII2} and {CoII2DyIII2} Tetranuclear Complexes

Magnetic Interaction Affecting the Zero-Field Single-Molecule Magnet Behaviors in Isomorphic {NiII2DyIII2} and {CoII2DyIII2} Tetranuclear Complexes
Wenyuan Wang, Sanping Chen, Hongshan Ke, Sheng Zhang, Min Li, Yiquan Zhang, Haipeng Wu, Guilin Zhuang, Qing Wei, Gang Xie
The local tetranuclear clusters exhibit a zigzag MII−LnIII−LnIII−MII arrangement featuring unique monophenoxo/diacetate bridging groups between MII and LnIII ion, significantly influencing the magnetic coupling and relaxation dynamics. The {NiII2DyIII2} complex reveals the same magnetic behavior under both zero field and an external magnetic field, confirming that ferromagnetic exchange is responsible for reducing the zero-field QTM. The phenomenon is not observed in the {CoII2DyIII2} case.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01840

DOI: 10.1021/acs.inorgchem.7b01840

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.