Hemilability of the 1,2-Bis(dimethylphosphino)ethane (dmpe) Ligand in Cp*Mo(NO)(κ2-dmpe)

5 years ago

Hemilability of the 1,2-Bis(dimethylphosphino)ethane (dmpe) Ligand in Cp*Mo(NO)(κ2-dmpe)

Peter Legzdins, Brian O. Patrick, Aaron S. Holmes, Taleah M. Levesque

As illustrated below, reactions of Cp*Mo(NO)(κ²-dmpe) with elemental sulfur and benzyl bromide result in the formation of complexes in which one end of the dmpe ligand was liberated from the molybdenum’s coordination sphere.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01733

DOI: 10.1021/acs.inorgchem.7b01733

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