3 years ago

A Shell-Shaped Carbon Architecture with High-Loading Capability for Lithium Sulfide Cathodes

A Shell-Shaped Carbon Architecture with High-Loading Capability for Lithium Sulfide Cathodes
Sheng-Heng Chung, Arumugam Manthiram, Pauline Han, Chi-Hao Chang
Lithium sulfide (Li2S) is considered a highly attractive cathode for establishing high-energy-density rechargeable batteries, especially due to its high charge-storage capacity and compatibility with lithium-metal-free anodes. Although various approaches have recently been pursued with Li2S to obtain high performance, formidable challenges still remain with cell design (e.g., low Li2S loading, insufficient Li2S content, and an excess electrolyte) to realize high areal, gravimetric, and volumetric capacities. This study demonstrates a shell-shaped carbon architecture for holding pure Li2S, offering innovation in cell-design parameters and gains in electrochemical characteristics. The Li2S core–carbon shell electrode encapsulates the redox products within the conductive shell so as to facilitate facile accessibility to electrons and ions. The fast redox-reaction kinetics enables the cells to attain the highest Li2S loading of 8 mg cm−2 and the lowest electrolyte/Li2S ratio of 9/1, which is the best cell-design specifications ever reported with Li2S cathodes so far. Benefiting from the excellent cell-design criterion, the core–shell cathodes exhibit stable cyclability from slow to fast cycle rates and, for the first time, simultaneously achieve superior performance metrics with areal, gravimetric, and volumetric capacities. A shell-shaped carbon electrode directly containing bulky lithium sulfide (Li2S) as the active-material core demonstrates optimized cell-design specifications with the highest Li2S loading (8 mg cm−2) and the lowest electrolyte/Li2S ratio (9/1). The cell design enables the high-loading cathodes to exhibit exceptionally high areal, gravimetric, and volumetric capacities with a high capacity retention of 90% over 200 cycles.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/aenm.201700537

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.