European Polymer Journal
European Polymer Journal
5 years ago

Highly soluble metal-organic polymers based on iron(II) clathrochelates and their gelation induced by sonication

Highly soluble metal-organic polymers based on iron(II) clathrochelates and their gelation induced by sonication
A series of clathrochelate polymers are reported by reacting iron(II) chloride with 9,9-dialkyl fluorene-2,7-diboronic acid and various vicinal dioxime units. The novel polymers were fully characterized by 1H and 13C nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), X-ray photoelectron spectroscopy (XPS), and UV–Vis absorption spectroscopy. The linearly-linked 2D organometallic polymers form oragnogel from 10wt% concentrations in organic solvents of low and medium polarity.

Publisher URL: www.sciencedirect.com/science

DOI: S0014305717310698

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