Metathesis of a UV imido complex: a route to a terminal UV sulfide

5 years ago

Metathesis of a UV imido complex: a route to a terminal UV sulfide

Marinella Mazzanti, Rory P. Kelly, Karsten Meyer, Rosario Scopelliti, Laurent Maron, Carlos Alvarez Lamsfus, Marta Falcone

The metathesis reaction of a U^V imido complex supported by sterically demanding tris(tert-butoxy)siloxide ligands with CS₂ afforded a terminal U^V thiocarbonate but metathesis with H₂S afforded the first example of a terminal U^V sulfide.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/FfD9eVJ_Uhg/C7SC01111C

DOI: 2017/SC/C7SC01111C

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