5 years ago

Synthesis of Triarylamines via Sequential C–N Bond Formation

Synthesis of Triarylamines via Sequential C–N Bond Formation
Mihai V. Popescu, Michael F. Greaney, Sachin G. Modha
A one-pot domino N-arylation protocol is described using diaryliodonium reagents under copper catalysis. The reaction uses both aryl groups of the diaryliodonium reagent to generate triarylamines starting from simple anilines, representing an atom-economical preparation of an important class of organic material building blocks.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01778

DOI: 10.1021/acs.joc.7b01778

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