3 years ago

Unusual C2h-Symmetric trans-1-(Bis-pyrrolidine)-tetra-malonate Hexa-Adducts of C60: The Unexpected Regio- and Stereocontrol Mediated by Malonate–Pyrrolidine Interaction

Unusual C2h-Symmetric trans-1-(Bis-pyrrolidine)-tetra-malonate Hexa-Adducts of C60: The Unexpected Regio- and Stereocontrol Mediated by Malonate–Pyrrolidine Interaction
Khalid Azmani, Josep M. Poblet, Alejandro J. Metta-Magana, Edison Castro, Amineh Aghabali, Marilyn M. Olmstead, Luis Echegoyen, Antonio Rodríguez-Fortea, Andrea Hernandez Garcia, Shuming Liu
A totally unanticipated regio- and stereo-isomerically pure C2h-symmetric trans-1-(bis-pyrrolidine)-tetra-malonate hexa-adduct of C60 was obtained via a topologically controlled method, followed by a 1,3-dipolar cycloaddition reaction. The graphic shows the fullerene C60 in the center and from this many other compounds can be obtained. More information can be found in the Full Paper by M. M. Olmstead, J. M. Poblet, L. Echegoyen et al. (DOI: 10.1002/chem.201702866).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201703999

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