3 years ago

Ruthenium Bisammine Complex and Its Reaction with Aryl Azides

Ruthenium Bisammine Complex and Its Reaction with Aryl Azides
Dae Young Bae, Young Ho Rhee, Jin Yong Park, Jaiwook Park, Yongjin Kim
A ruthenium bisammine complex was formed in the reaction of ruthenium 1,4-dibenzyltetraazadiene complex with primary amines at room temperature, which was a versatile precursor for the synthesis of various Ru(II) complexes through ligand exchange reactions. In the reaction with azidobenzene, ruthenium 1,4-diphenyltetraaza-1,3-diene complex was formed, while ruthenium imido complexes were given in the reaction with bulky aryl azides such as 2-azido-1,3-dimethylbenzene and 2-azido-1,3-diisopropylbenzene. The ruthenium imido complexes showed high catalytic activity in the reaction of alkyl azides with primary amines to afford N-substituted imines.

Publisher URL: http://dx.doi.org/10.1021/acs.organomet.7b00403

DOI: 10.1021/acs.organomet.7b00403

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