Analytical Chemistry
Analytical Chemistry
3 years ago

Magnetophoretic Mole-Ratio Method

Magnetophoretic Mole-Ratio Method
Hitoshi Watarai, Jayue Chen
The principle of the mole-ratio method utilizing magnetophoretic velocimetry was demonstrated for the first time. The feasibility of the magnetophoretic mole-ratio method was studied for the determination of the stoichiometry of the complexes formed between a hydrophobic phosphate ligand adsorbed in mesoporous hydrophobic silica particles and paramagnetic metal ions of Co(II), Tb(III), and Dy(III) in aqueous solutions. The present method is a nonspectroscopic method and carried out by a simple magnetic device.

Publisher URL: http://dx.doi.org/10.1021/acs.analchem.7b00999

DOI: 10.1021/acs.analchem.7b00999

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