Crystal Growth & Design
Crystal Growth & Design
5 years ago

Photoluminescent Lanthanide-Organic Framework Based on a Tetraphosphonic Acid Linker

Photoluminescent Lanthanide-Organic Framework Based on a Tetraphosphonic Acid Linker
João Rocha, Filipe A. Almeida Paz, Luís D. Carlos, Duarte Ananias, Ricardo F. Mendes
The metal−organic framework family [Ln2(SO4)2(H6htp)(H2O)4]·10H2O [Ln3+ = Eu3+, Sm3+, and Gd3+; hexamethylenediamine-N,N,N′,N′-tetrakis(methylphosphonic acid = H8htp] was obtained by microwave heating at moderate temperatures (80 °C) and low reaction time (15 min). The reaction was carried out in aqueous medium in the presence of sulfuric acid. Materials consist of a 3D network with cavities filled with solvent water molecules.

Publisher URL: http://dx.doi.org/10.1021/acs.cgd.7b00667

DOI: 10.1021/acs.cgd.7b00667

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.