Organometallic mechanisms: Measuring up with the early metals
Mathematically modelling metal–ligand bonding in late transition-metal complexes has been an important tool in catalyst development — although lacking for early transition metals such as Cr and Ti. Now, a simple method for measuring ligand donor properties promises to elevate high-valent early transition metal catalysis to the same level.
Publisher URL: https://www.nature.com/articles/nchem.2851
DOI: 10.1038/nchem.2851
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