Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Direct Functionalization of C−H Bonds by Iron, Nickel, and Cobalt Catalysis

Direct Functionalization of C−H Bonds by Iron, Nickel, and Cobalt Catalysis
Gerit Pototschnig, Nuno Maulide, Michael Schnürch
Non-precious-metal-catalyzed reactions are of increasing importance in chemistry due to the outstanding ecological and economic properties of these metals. In the subfield of metal-catalyzed direct C−H functionalization reactions, recent years have shown an increasing number of publications dedicated to this topic. Nickel, cobalt, and last but not least iron, have started to enter a field which was long dominated by precious metals such as palladium, rhodium, ruthenium, and iridium. The present review article summarizes the development of iron-, nickel-, and cobalt-catalyzed C−H functionalization reactions until the end of 2016, and discusses the scope and limitations of these transformations. Worth their weight: Non-precious-metal- catalyzed direct C−H functionalization reactions are of increasing importance in chemistry due to the outstanding ecological and economic potential. The present Review article summarizes the development of iron, nickel, and cobalt-catalyzed C−H activation reactions and discusses the scope and limitations of these transformations.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201605657

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