Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
5 years ago

Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal–Organic Frameworks

Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal–Organic Frameworks
Mian Li, Ying Zhang, Dan Li, Jun-Hao Wang, Shu Yan, Xian-Ming Zhang
Owing to their extraordinary robustness and high porosity, chromium(III)-based metal–organic frameworks (Cr-MOFs) have great potential but they are currently difficult to synthesize. In their Communication (DOI: 10.1002/anie.201701217), J. H. Wang, X. M. Zhang et al. describe the preparation of a variety of Cr-MOFs from the corresponding Fe-MOFs under mild conditions by solvent-assisted metal metathesis. This efficient and versatile strategy constitutes a promising route for the synthesis of stable MOFs.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201703997

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