Organic Letters
Organic Letters
5 years ago

Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis

Cross-Coupling Reactions of Aryldiazonium Salts with Allylsilanes under Merged Gold/Visible-Light Photoredox Catalysis
Nitin T. Patil, Pramod S. Mali, Manjur O. Akram
A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b01148

DOI: 10.1021/acs.orglett.7b01148

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