5 years ago

Bu4NI-Catalyzed Oxygen-Centered Radical Addition between Acyl Peroxides and Isocyanides

Bu4NI-Catalyzed Oxygen-Centered Radical Addition between Acyl Peroxides and Isocyanides
Cuiting Li, Kai Wang, Hao Ding, Hong Tang, Aiwen Lei, Meng Gao, Yang Li, Lingen Yang, Meng Chen
A novel oxygen-centered radical addition between acyl peroxides and isocyanides has been developed. A diverse collection of valuable arylcarboxyamides were easily synthesized by this protocol. From the preliminary mechanistic study, the elimination of carbon dioxide affords the product via an intramolecular rearrangement.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b01272

DOI: 10.1021/acs.orglett.7b01272

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