Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
4 years ago

Chemistry of the 5g Elements: Relativistic Calculations on Hexafluorides

Chemistry of the 5g Elements: Relativistic Calculations on Hexafluorides
Pekka Pyykkö, Jean-Pierre Dognon
A Periodic System was proposed for the elements 1–172 by Pyykkö on the basis of atomic and ionic calculations. In it, the elements 121–138 were nominally assigned to a 5g row. We now perform molecular, relativistic four-component DFT calculations and find that the hexafluorides of the elements 125–129 indeed enjoy occupied 5g states. The shape of things to come: Molecular, relativistic four-component DFT calculations show that the hexafluorides of the elements 125–129 have occupied 5g states, the picture shows the shape of the 5g atomic orbital (m=0–4).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201701609

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.