3 years ago

Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes

Manganese Silylene Hydride Complexes: Synthesis and Reactivity with Ethylene to Afford Silene Hydride Complexes
Jeffrey S. Price, David J. H. Emslie, James F. Britten
Manganese and hydrogen are two key elements used by D. J. H. Emslie et al. in their Communication (DOI: 10.1002/anie.201700863). The reactions described sequentially introduce silicon and carbon into the core of the molecule, which is represented by an inukshuk, a stone landmark used by peoples of the Arctic region, including northern Canada. On the left-hand side, the climb of two silylene hydride molecules towards the core of the final product, represented by “Hounds Tooth” in British Columbia (Canada), is shown.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201704013

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