Tetrahedron
Tetrahedron
5 years ago

Microwave assisted solvent- and catalyst-free three-component synthesis of NH-1,2,3-triazoloimines

Microwave assisted solvent- and catalyst-free three-component synthesis of NH-1,2,3-triazoloimines
Highly efficient microwave-assisted solvent- and catalyst-free multicomponent synthesis of 5-R-imino-[4-trialkylsilyl(germyl)]-1H-1,2,3-triazoles from Si/Ge-substituted propynals, trimethylsilyl azide and functionalized primary amines has been developed. In the case of 2-aminoethanethiol, 4-element substituted 5-(1,3-thiazolan-2-yl)-1H-1,2,3-triazoles have been obtained. Their heterolysis by MeOH at room temperature leads to the corresponding triazoloimines in high yield.

Publisher URL: www.sciencedirect.com/science

DOI: S0040402017305781

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.