4 years ago

Asymmetric total synthesis of (−)-perforanoid A

Asymmetric total synthesis of (−)-perforanoid A
Asymmetric total synthesis of (−)-perforanoid A, a novel limonoid isolated from the leaves of Harrisonia perforata, has been achieved. The key features of our total synthesis include the Rh-catalyzed intramolecular Pauson–Khand reaction of an allene and an alkene, the Pd-catalyzed lactonization of an allylic alcohol with a vinyl ether, and the enantioselective alkenylation of 3-furaldehyde.

Publisher URL: www.sciencedirect.com/science

DOI: S0040402017303290

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