Journal of the American Chemical Society
Journal of the American Chemical Society
5 years ago

Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides

Nickel-Catalyzed C-Alkylation of Nitroalkanes with Unactivated Alkyl Iodides
Donald A. Watson, Sina Rezazadeh, Vijayarajan Devannah
Enabled by nickel catalysis, a mild and general catalytic method for C-alkylation of nitroalkanes with unactivated alkyl iodides is described. Compatible with primary, secondary, and tertiary alkyl iodides; and tolerant of a wide range of functional groups, this method allows rapid access to diverse nitroalkanes.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b04312

DOI: 10.1021/jacs.7b04312

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