Journal of Organic Chemistry
Journal of Organic Chemistry
5 years ago

Palladium-Catalyzed ortho–C-H Arylation of Acetophenone Oxime Ethers with Aryl Pinacol Boronic Esters

Palladium-Catalyzed ortho–C-H Arylation of Acetophenone Oxime Ethers with Aryl Pinacol Boronic Esters
Chin-Fa Lee, Kai Du, Shao-Chien Wang, Daggula Mallikarjuna Reddy
We report an efficient palladium-catalyzed ortho–C-H arylation of acetophenone oxime ethers with aryl pinacol boronic esters, leading to the synthesis of biaryl derivatives in good yields. Sequential process of iridium-catalyzed C–H borylation and palladium-catalyzed ortho–C-H arylation directed to access functionalized arenes.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b01524

DOI: 10.1021/acs.joc.7b01524

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