Chemical Science
Chemical Science
5 years ago

Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions

Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions
Mattes Holsten, Veronica Papa, Rosa Adam, Jose R. Cabrero-Antonino, Matthias Beller, Kathrin Junge
The first general and efficient non-noble metal-catalysed reductive C2-alkoxylation of cyclic imides (phthalimides and succinimides) is presented. Crucial for the success is the use of [Co(BF4)2[middle dot]6H2O/triphos (L1)] combination and no external additives are required.

Publisher URL: http://feeds.rsc.org/~r/rss/SC/~3/JsIaeY81s6w/C7SC01175J

DOI: 2017/SC/C7SC01175J

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