Journal of the American Chemical Society
Journal of the American Chemical Society
5 years ago

Slow Magnetic Relaxation in a Lanthanide-[1]Metallocenophane Complex

Slow Magnetic Relaxation in a Lanthanide-[1]Metallocenophane Complex
Nattamai S. Bhuvanesh, Trevor P. Latendresse, Michael Nippe
The first example of a lanthanide metallocenophane complex has been isolated as [Li(THF)4][DyFc3Li2(THF)2] (1). The molecular structure of complex 1 differs dramatically from those of main group and transition metal ferrocenophane complexes and features a distorted trigonal prismatic geometry around the Dy(III) ion and close intramolecular Dy···Fe distances. Furthermore, complex 1 exhibits all characteristics of a soft single-molecule magnet.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b01499

DOI: 10.1021/jacs.7b01499

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