Angewandte Chemie - International Edition
Angewandte Chemie - International Edition
4 years ago

Inside Cover: Efficient Palladium-Catalyzed Alkoxycarbonylation of Bulk Industrial Olefins Using Ferrocenyl Phosphine Ligands (Angew. Chem. Int. Ed. 19/2017)

Inside Cover: Efficient Palladium-Catalyzed Alkoxycarbonylation of Bulk Industrial Olefins Using Ferrocenyl Phosphine Ligands (Angew. Chem. Int. Ed. 19/2017)
Xianjie Fang, Kaiwu Dong, Helfried Neumann, Anke Spannenberg, Rui Sang, Ralf Jackstell, Matthias Beller, Robert Franke
Game-changing ligand design for alkene alkoxycarbonylations: In their Communication on page 5267 ff., M. Beller and co-workers present a novel class of ferrocenyl ligands for improved alkene carbonylations. These phosphines with sterically hindered and amphoteric groups on the P atoms actively take part in the catalysis. They are easily synthesized and display higher activity and durability in alkoxycarbonylations of bulk olefins under milder conditions.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201702485

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