Photosensitization Behavior of Ir(III) Complexes in Selective Reduction of CO2 by Re(I)-Complex-Anchored TiO2 Hybrid Catalyst

4 years ago

Photosensitization Behavior of Ir(III) Complexes in Selective Reduction of CO2 by Re(I)-Complex-Anchored TiO2 Hybrid Catalyst

Chul Hoon Kim, Dae Won Cho, Ha-Yeon Cheong, Ho-Jin Son, Yang-Jin Cho, Sang Ook Kang, So-Yoen Kim, Chyongjin Pac

The binary hybrid catalytic system (photosensitizer + TiO₂/Re(I)) serves the first direct route from light-capturing by homogeneous photosensitization to heterogeneous catalytic site, showing efficient photocatalytic CO₂ to CO conversion efficiency (a turnover number of >300 for 10 h).

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01963

DOI: 10.1021/acs.inorgchem.7b01963

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