Inorganic Chemistry
Inorganic Chemistry
5 years ago

Dysprosium Heteroleptic Corrole-Phthalocyanine Triple-Decker Complexes: Synthesis, Crystal Structure, and Electrochemical and Magnetic Properties

Dysprosium Heteroleptic Corrole-Phthalocyanine Triple-Decker Complexes: Synthesis, Crystal Structure, and Electrochemical and Magnetic Properties
Zhongping Ou, Dongdong Qi, Kang Wang, Weihua Zhu, Chiming Wang, Sen Yan, Junshan Sun, Suyuan Zeng, Cheng He, Lei Gong, Guifen Lu
The first example of dysprosium complexes incorporating a corrole ligand, Dy2[Pc(OC5H11)8]2[Cor(FPh)3] (1) and Dy2[Pc(OC5H11)8]2[Cor(ClPh)3] (2), was synthesized and characterized by a variety of techniques, including single-crystal X-ray diffraction, electrochemistry, and magnetism. The present work can further enrich the “periodic table of corrole complexes” and explore the functionalities of these types of triple-decker complexes.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01060

DOI: 10.1021/acs.inorgchem.7b01060

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