Inorganic Chemistry
Inorganic Chemistry
3 years ago

Reactivity of Fe and Ru Complexes of Picolyl-Substituted N-Heterocyclic Carbene Ligand: Diverse Coordination Modes and Small Molecule Binding

Reactivity of Fe and Ru Complexes of Picolyl-Substituted N-Heterocyclic Carbene Ligand: Diverse Coordination Modes and Small Molecule Binding
Datong Song, Qiuming Liang
We report the reactivity of iron(II) and ruthenium(II) half-sandwich complexes bearing a picolyl-NHC (NHC = N-heterocyclic carbene) ligand toward bases and small molecules (CO, N2, H2, O2). The monodeprotonated picolyl-NHC ligand displays isomerism with diverse coordination modes.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01918

DOI: 10.1021/acs.inorgchem.7b01918

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