3 years ago

Inside Back Cover: Synthesis of Poly(arylene vinylene)s with Different End Groups by Combining Acyclic Diene Metathesis Polymerization with Wittig-type Couplings (Angew. Chem. Int. Ed. 19/2017)

Inside Back Cover: Synthesis of Poly(arylene vinylene)s with Different End Groups by Combining Acyclic Diene Metathesis Polymerization with Wittig-type Couplings (Angew. Chem. Int. Ed. 19/2017)
Shunsuke Sueki, Kotohiro Nomura, Tomonari Miyashita, Mikiko Kunisawa
The synthesis of poly(arylene vinylene)s with different end groups is described by K. Nomura and co-workers in their Communication on page 5288 ff. The end-functionalized poly(9,9′-dialkylfluorene vinylene) derivatives (EF-PFVs) were obtained by 1) synthesizing EF-PFVs with vinyl chain ends by acyclic diene metathesis polymerization using a molybdenum catalyst and termination with an aldehyde and 2) subsequent olefin metathesis of the vinyl group followed by Wittig-type coupling with another aldehyde.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201703019

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