ACS Macro Letters
ACS Macro Letters
5 years ago

Light-Mediated Reversible Assembly of Polymeric Colloids

Light-Mediated Reversible Assembly of Polymeric Colloids
Marcus Weck, Xiaolong Zheng, Elizabeth Elacqua
This contribution highlights the functionalization of colloidal particles featuring high-symmetry patches with telechelic block copolymers and subsequent reversible self-assembly of the resulting particles into longer chain and branched structures using host–guest complexation. The 3-(trimethoxysilyl)propyl methacrylate (TPM)-based anisotropic particles, obtained through a cluster-encapsulation process, consist of poly(styrene) patches and are site-specifically functionalized with block copolymers bearing pendant viologen or azobenzene motifs. Key to the design is the engineering of heterotelechelic α-hydroxy-ω-formyl-poly(norbornene)s via ring-opening metathesis polymerization (ROMP). The block copolymers feature both main chain anchor points to the particle surface, as well as orthogonal reactive sites for cyanine dye conjugation. The polymeric particles undergo directed and reversible supramolecular assembly in the presence of the host cucurbit[8]uril.

Publisher URL: http://dx.doi.org/10.1021/acsmacrolett.7b00539

DOI: 10.1021/acsmacrolett.7b00539

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