3 years ago

A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores

A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores
Feng-Shou Xiao, Yanqin Wang, Liang Wang, Jian Zhang, Bruce C. Gates, Yi Shao
Palladium nanoparticles were fixed inside zeolite crystals to obtain a catalyst with superior selectivity in the hydrogenation of substituted nitroarenes with multiple reducible groups. In their Communication (DOI: 10.1002/anie.201703938), L. Wang, F.-S. Xiao, and co-workers show that the high selectivity is due to the sterically controlled adsorption of the nitroarenes on the palladium nanoparticles within the zeolite micropores.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/anie.201705761

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