3 years ago

Photocatalytic CO2 Reduction by Periodic Mesoporous Organosilica (PMO) Containing Two Different Ruthenium Complexes as Photosensitizing and Catalytic Sites

Photocatalytic CO2 Reduction by Periodic Mesoporous Organosilica (PMO) Containing Two Different Ruthenium Complexes as Photosensitizing and Catalytic Sites
Yoshifumi Maegawa, Yusuke Kuramochi, Hitoshi Ishida, Kyohei Kitamura, Shinji Inagaki, Masato Sekine, Soichi Shirai, Yasutomo Goto
Periodic mesoporous organosilicas (PMOs) modified with two different ruthenium complexes were synthesized and their catalytic activities for photochemical CO2 reduction were investigated. In the catalysis, [Ru(bpy)3]- and trans(Cl)-[Ru(bpy)(CO)2Cl2]-type complexes act as the photosensitizer and the catalyst, respectively, to produce CO and HCOO−. More information can be found in the Full Paper by S. Inagaki, H. Ishida et al. (DOI: 10.1002/chem.201701466).

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201702135

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