Inorganic Chemistry
Inorganic Chemistry
3 years ago

Cobalt(II) Ions Connecting [CoII4] Helicates into a 2-D Coordination Polymer Showing Slow Relaxation of the Magnetization

Cobalt(II) Ions Connecting [CoII4] Helicates into a 2-D Coordination Polymer Showing Slow Relaxation of the Magnetization
Paula Cucos, Delia Patroi, Catalin Maxim, Lorenzo Sorace, Andrea Caneschi, Marius Andruh, Sergiu Shova
Two novel coordination polymers have been constructed from anionic triple-stranded {CoII4} helicates, which are are connected in 1 by sodium ions and in 2 by sodium and cobalt(II) ions. The magnetic behavior of 2 is dominated at low temperature by the single CoII ions that show slow relaxation of the magnetization.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01640

DOI: 10.1021/acs.inorgchem.7b01640

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