Inorganic Chemistry
Inorganic Chemistry
5 years ago

Cationic and Anionic Disorder in CZTSSe Kesterite Compounds: A Chemical Crystallography Study

Cationic and Anionic Disorder in CZTSSe Kesterite Compounds: A Chemical Crystallography Study
Maria Teresa Caldes, Pierre Bais, Michaël Paris, Alain Lafond, Catherine Guillot-Deudon, Bernadette Domengès, Pierre Fertey
A standard and resonant XRD, 77Se NMR, and TEM multiscale investigation of mixed sulfoselenide CZTS derived compounds has been carried out. The CZTSe-CZTS system behaves as a solid solution with the kesterite crystal structure. The Cu/Zn and the S/Se distributions appear not to be long-range phenomena regardless of the thermal history of the samples, while there is clear evidence from NMR and TEM investigation of a local ordering.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01791

DOI: 10.1021/acs.inorgchem.7b01791

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