5 years ago

Dual Role of H2O2 in Palladium-Catalyzed Dioxygenation of Terminal Alkenes

Dual Role of H2O2 in Palladium-Catalyzed Dioxygenation of Terminal Alkenes
Jiuzhong Huang, Huanfeng Jiang, Lu Ouyang, Weigao Hu, Wanqing Wu, Jianxiao Li, Jia Zheng
A palladium-catalyzed, environmentally friendly dioxygenation reaction of simple alkenes has been developed that enabled rapid assembly of valuable α-hydroxy ketones with high atom economy. Notably, control experiments and 18O isotope-labeling experiments established that H2O2 played a dominant dual role in this transformation.

Publisher URL: http://dx.doi.org/10.1021/acs.orglett.7b01228

DOI: 10.1021/acs.orglett.7b01228

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