5 years ago

Salen-Based Covalent Organic Framework

Salen-Based Covalent Organic Framework
Yun-Xiang Ma, Wei Wang, Li-Hua Li, Xiao-Lin Feng, Xiao-Hui Cui, San-Yuan Ding
The Salen unit represents one of the most important ligands in coordination chemistry. We report herein the first example of a Salen-based covalent organic framework (COF), in which both the construction of the COF structure and the functionalization with Salen moieties have been realized in a single step. Due to its structural uniqueness, the obtained COF material, Salen-COF, possesses high crystallinity and excellent stability. Based on this, a series of metallo-Salen-based COFs were prepared via metalation for further applications.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b01523

DOI: 10.1021/jacs.7b01523

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