Chemistry of Materials
Chemistry of Materials
3 years ago

Heat- and Gas-Induced Transformation in CH3NH3PbI3 Perovskites and Its Effect on the Efficiency of Solar Cells

Heat- and Gas-Induced Transformation in CH3NH3PbI3 Perovskites and Its Effect on the Efficiency of Solar Cells
Sylwia Ptasinska, Weixin Huang, Subha Sadhu
Following the remarkable success of the application of CH3NH3PbI3 perovskites in photovoltaics, a great focus has been placed on their stability to improve their optoelectronic properties and seek commercial production. To gain a better understanding of their thermal stability, we investigated the chemical, morphological, and photovoltaic transformations of CH3NH3PbI3 perovskites under elevated temperatures and various controlled atmospheric conditions (vacuum, 1 mbar O2, and 1 mbar H2O). A temperature-dependent study showed that CH3NH3PbI3 decomposed to PbI2 with the release of CH3NH2 and HI under low-temperature annealing (25–150 °C). Further annealing resulted in the formation of metallic lead (Pb0) under vacuum and Pb oxides and hydroxides under an O2 or H2O pressure. Moreover, the sublimation of Pb-based compounds occurred at temperatures above 150 °C, causing structural changes, which resulted in a decrease in the power conversion efficiency of the solar cell. A time-dependent study showed that, compared with vacuum conditions, the addition of O2 or H2O accelerated the degradation of the perovskite films.

Publisher URL: http://dx.doi.org/10.1021/acs.chemmater.7b03243

DOI: 10.1021/acs.chemmater.7b03243

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