3 years ago

Frontispiece: A Consecutive C−H Functionalization Triggered by Oxidation of Active sp3 C−H Bonds: Construction of 3,4-Dihydroquinoline-3-one Derivatives

Frontispiece: A Consecutive C−H Functionalization Triggered by Oxidation of Active sp3 C−H Bonds: Construction of 3,4-Dihydroquinoline-3-one Derivatives
Xiaodong Jia, Pengfei Li, Qian Chen, Yu Yuan, Honghe Ji, Xiaofei Liu, Wentao Hou, Yu Shao
Construction of 3,4-dihydroquinoline-3-ones is achieved by radical cation-initiated aerobic oxidation. In this transformation, the active sp3 C−H bonds of glycines act as the “Achilles′ heel”, triggering the consecutive oxidation of the inert C−H bonds. Furthermore, one heterocylic ring with a quaternary carbon center is also constructed. More information can be found in the Communication by X. Jia et al. on page 12980 ff.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201785363

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