3 years ago

Inside Back Cover: How Does CeIII Nitrate Dissolve in a Protic Ionic Liquid? A Combined Molecular Dynamics and EXAFS Study (Chem. Eur. J. 35/2017)

Inside Back Cover: How Does CeIII Nitrate Dissolve in a Protic Ionic Liquid? A Combined Molecular Dynamics and EXAFS Study (Chem. Eur. J. 35/2017)
Paola D'Angelo, Valentina Migliorati, Alessandra Serva, Riccardo Spezia
A combined molecular dynamics and X-ray absorption spectroscopy investigation shows that the CeIII ion in the protic ionic liquid ethylammonium nitrate is coordinated by nitrate ions, both as monodentate and bidentate ligands, arranged in an icosahedral structure. The metal ions are solvated within the polar domains of the ethylammonium nitrate nanostructure and the dissolved Ce(NO3)3 induces almost no reorganization of the pre-existing structure upon solubilization. More information can be found in the Full Paper by P. D′Angelo et al. on page 8424.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201701561

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