3 years ago

Boron–Heteroatom Addition Reactions via Borylative Heterocyclization: Oxyboration, Aminoboration, and Thioboration

Boron–Heteroatom Addition Reactions via Borylative Heterocyclization: Oxyboration, Aminoboration, and Thioboration
Kim N. Tu, Suzanne A. Blum, Adena Issaian
Organoboron compounds and heterocycles are powerful building blocks and precursors for organic synthesis, including for drug discovery and agrochemical and material synthesis. The common strategy for the synthesis of borylated heterocycles involves two separate synthetic steps: first, synthesis of the heterocyclic core, and second, borylation of the core through established methods such as transition-metal-catalyzed C–H or C–X activation/borylation or lithiation/borylation.

Publisher URL: http://dx.doi.org/10.1021/acs.accounts.7b00365

DOI: 10.1021/acs.accounts.7b00365

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