3 years ago

Light-Induced Spin State Switching and Relaxation in Spin Pairs of Copper(II)–Nitroxide Based Molecular Magnets

Light-Induced Spin State Switching and Relaxation in Spin Pairs of Copper(II)–Nitroxide Based Molecular Magnets
Sergey L. Veber, Galina V. Romanenko, Matvey V. Fedin, Victor I. Ovcharenko, Natalia A. Artiukhova, Svyatoslav E. Tolstikov, Sergey V. Tumanov
Larger structural changes upon light-induced spin state switching drastically increase the stability of corresponding photoinduced states. This has been for the first time clearly demonstrated here for copper(II)−nitroxide based molecular magnets, and can find broader applicability for spin-crossover and spin-crossover-like materials.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01689

DOI: 10.1021/acs.inorgchem.7b01689

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