Inorganic Chemistry
Inorganic Chemistry
5 years ago

A Modern Twist to a Classic Synthetic Route: Ph3Bi-Based Redox Transmetalation Protolysis (RTP) for the Preparation of Barium Metalorganic Species

A Modern Twist to a Classic Synthetic Route: Ph3Bi-Based Redox Transmetalation Protolysis (RTP) for the Preparation of Barium Metalorganic Species
Ana Torvisco, Anna O’Brien, Karin Ruhlandt-Senge, Melanie Wolf, Philip C. Andrews, Yuriko Takahashi, Glen B. Deacon, Miriam M. Gillett-Kunnath
Mechanistic studies demonstrate that Ph3Bi-based redox transmetalation/protolysis (RTP) for the preparation of barium metalorganic species is a highly attractive alternative to traditional synthetic approaches. The versatility of this one-pot method works well for a range of ligand acidities and bulk. Ph3Bi-based RTP is especially useful for less acidic and sterically demanding ligands where direct metalation fails. In these cases, RTP provides reaction rates up to 30 times faster than direct metalation.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b00764

DOI: 10.1021/acs.inorgchem.7b00764

You might also like
Discover & Discuss Important Research

Keeping up-to-date with research can feel impossible, with papers being published faster than you'll ever be able to read them. That's where Researcher comes in: we're simplifying discovery and making important discussions happen. With over 19,000 sources, including peer-reviewed journals, preprints, blogs, universities, podcasts and Live events across 10 research areas, you'll never miss what's important to you. It's like social media, but better. Oh, and we should mention - it's free.

  • Download from Google Play
  • Download from App Store
  • Download from AppInChina

Researcher displays publicly available abstracts and doesn’t host any full article content. If the content is open access, we will direct clicks from the abstracts to the publisher website and display the PDF copy on our platform. Clicks to view the full text will be directed to the publisher website, where only users with subscriptions or access through their institution are able to view the full article.