Inorganic Chemistry
Inorganic Chemistry
5 years ago

Understanding the Coordination Modes of [Cu(acac)2(imidazole)n=1,2] Adducts by EPR, ENDOR, HYSCORE, and DFT Analysis

Understanding the Coordination Modes of [Cu(acac)2(imidazole)n=1,2] Adducts by EPR, ENDOR, HYSCORE, and DFT Analysis
Damien M. Murphy, Mario Chiesa, Nadine Ritterskamp, Emma Richards, James A. Platts, Andrea Folli, Katherine Sharples
Electron paramagnetic resonance, electron nuclear double resonance, hyperfine sublevel correlation spectroscopy, and density functional theory were used to study the coordination of imidazole to a model [Cu(acac)2] complex, revealing the formation of the trans-equatorial [Cu(acac)2Im2] bis-adduct at high copper to Im ratios.

Publisher URL: http://dx.doi.org/10.1021/acs.inorgchem.7b01874

DOI: 10.1021/acs.inorgchem.7b01874

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