3 years ago

Transition-Metal-Free and Oxidant-Free Cross-Coupling of Arylhydrazines with Disulfides: Base-Promoted Synthesis of Unsymmetrical Aryl Sulfides

Transition-Metal-Free and Oxidant-Free Cross-Coupling of Arylhydrazines with Disulfides: Base-Promoted Synthesis of Unsymmetrical Aryl Sulfides
Akiya Ogawa, Mitsutaka Imoto, Takuya Naka, Akihiro Nomoto, Masatoshi Mihara, Takeo Nakai, Motonori Takeda, Toshihide Taniguchi, Takumi Mizuno
A novel synthesis of unsymmetrical aryl sulfides, which requires no transition metal catalyst and no oxidant, was developed. This base-promoted cross-coupling reaction proceeded using arylhydrazines and 1 equiv amount of disulfides under inert gas conditions to afford the unsymmetrical aryl sulfides in good yields.

Publisher URL: http://dx.doi.org/10.1021/acs.joc.7b00767

DOI: 10.1021/acs.joc.7b00767

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