3 years ago

A Mononuclear Nonheme Iron(V)-Imido Complex

A Mononuclear Nonheme Iron(V)-Imido Complex
Yong-Min Lee, Takehiro Ohta, Takashi Ogura, Sora Park, Seungwoo Hong, Kyle D. Sutherlin, Xiaoyan Lu, James J. Yan, Soojeong Jang, Anil Kumar Vardhaman, Edward I. Solomon, Wonwoo Nam
Mononuclear nonheme iron(V)-oxo complexes have been reported previously. Herein, we report the first example of a mononuclear nonheme iron(V)-imido complex bearing a tetraamido macrocyclic ligand (TAML), [(TAML)FeV(NTs)] (1). The spectroscopic characterization of 1 revealed an S = 1/2 Fe(V) oxidation state, an Fe—N bond length of 1.65(4) Å, and an Fe—N vibration at 817 cm–1. The reactivity of 1 was demonstrated in C—H bond functionalization and nitrene transfer reactions.

Publisher URL: http://dx.doi.org/10.1021/jacs.7b04695

DOI: 10.1021/jacs.7b04695

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