Chemistry - A European Journal
Chemistry - A European Journal
5 years ago

Inside Back Cover: Synthesis, Electronic Structure, and Reactivities of Two-Sulfur-Stabilized Carbones Exhibiting Four-Electron Donor Ability (Chem. Eur. J. 36/2017)

Inside Back Cover: Synthesis, Electronic Structure, and Reactivities of Two-Sulfur-Stabilized Carbones Exhibiting Four-Electron Donor Ability (Chem. Eur. J. 36/2017)
Ryo Iijima, Shigeru Nagase, Tomohito Morosaki, Wei-Wei Wang, Takayoshi Fujii, Tsubasa Suzuki
Two-sulfur-stabilized carbones: the presence of a “second” lone pair on a coordinated atom significantly enhances the electron-donating ability of the central carbon in carbones. The strongest electron-donating ability of bis(sulfane)carbon(0) (BSC) among the two-sulfur-stabilized carbones was demonstrated by the generation of diprotonated salt BSC⋅H2+. The C-digold(I) complexes of two-sulfur-stabilized carbones provide the first experimental proof of their four-electron-donating ability. More information can be found in the Full Paper by T. Fujii et al. on page 8694.

Publisher URL: http://onlinelibrary.wiley.com/resolve/doi

DOI: 10.1002/chem.201701397

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