Chemical Communications
Chemical Communications
5 years ago

A synthetic co-crystal prepared by cooperative single-crystal-to-single-crystal solid-state Diels-Alder reaction

A synthetic co-crystal prepared by cooperative single-crystal-to-single-crystal solid-state Diels-Alder reaction
M. A. Fernandes, S. Khorasani
Solid-state Diels-Alder reaction in a 2 : 1 donor to acceptor charge-transfer complex leads to a synthetic co-crystal composed of product and unreacted donor. Analysis of close contacts and DFT energy calculations indicate that the reaction occurs cooperatively where the arrangement of molecules shown in (ii) is favoured.

Publisher URL: http://feeds.rsc.org/~r/rss/CC/~3/O-J-QxmlNww/C6CC07628A

DOI: 2017/CC/C6CC07628A

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