Tetrahedron
Tetrahedron
5 years ago

Nickel-catalyzed cross-coupling of aryl or 2-menaphthyl quaternary ammonium triflates with organoaluminum reagents

Nickel-catalyzed cross-coupling of aryl or 2-menaphthyl quaternary ammonium triflates with organoaluminum reagents
The cross-coupling of aryltrimethylammonium triflates with AlMe3 and β-H-containing trialkylaluminums was performed in dioxane at 110 °C under catalysis of (dppp)NiCl2 to afford alkylated arenes. The cross-coupling of 2-menaphthyltrimethylammonium triflate with trialkylaluminums and 1-naphthyltrimethylammonium triflate with triarylaluminums was also carried out respectively under the same conditions.

Publisher URL: www.sciencedirect.com/science

DOI: S0040402017306233

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